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trans-Bis(acetato-κO)diaquabis(2-aminopyrazine-κN4)manganese(II) dihydrate

Authors :
Shan Gao
Seik Weng Ng
Source :
Acta Crystallographica Section E, Vol 67, Iss 8, Pp m1140-m1140 (2011)
Publication Year :
2011
Publisher :
International Union of Crystallography, 2011.

Abstract

The MnII atom in the title compound, [Mn(CH3COO)2(C4H5N3)2(H2O)2]·2H2O, is situated on a center of inversion and shows an octahedral coordination polyhedron made up by four O atoms and two N atoms. The octahedron is somewhat tetragonally distorted owing to the longer Mn—N bond [2.323 (3) Å]. The mononuclear complex molecule and uncoordinated water molecules are linked by O—H...N, N—H...O and O—H...O hydrogen bonds, generating a three-dimensional network.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
67
Issue :
8
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.86731cd4b3f4e2faf53001139d465c9
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536811028583