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Di-μ-bromido-bis{[N,N-dimethyl-N′-(thiophen-2-ylmethylidene)ethane-1,2-diamine]copper(I)]}

Authors :
Christopher Goh
Andre P. Martinez
Jerry P. Jasinski
Amanda C. Keeley
Zachary D. Remillard
Source :
Acta Crystallographica Section E, Vol 68, Iss 5, Pp m691-m692 (2012)
Publication Year :
2012
Publisher :
International Union of Crystallography, 2012.

Abstract

In the crystal structure of the title compound, [Cu2Br2(C9H14N2S)2], the molecule resides about a crystallographic inversion center. The coordination sphere around each copper ion has a distorted tetrahedral geometry, with ligation by two bridging bromide ions, an amine N atom and an imine N atom. The thiophene ring is disordered over two sites, with occupancies of 0.719 (3) and 0.281 (3). Weak C—H...π interactions feature in the crystal packing.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
68
Issue :
5
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.85dc514982824b7fb0cf091be2b32684
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536812017989