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Structure, Luminescence and Temperature Detection Capability of [C(NH2)3]M(HCOO)3 (M = Mg2+, Mn2+, Zn2+) Hybrid Organic–Inorganic Formate Perovskites Containing Cr3+ Ions
- Source :
- Sensors, Vol 23, Iss 14, p 6259 (2023)
- Publication Year :
- 2023
- Publisher :
- MDPI AG, 2023.
-
Abstract
- Metal-organic frameworks are of great interest to scientists from various fields. This group also includes organic–inorganic hybrids with a perovskite structure. Recently their structural, phonon, and luminescent properties have been paid much attention. However, a new way of characterization of these materials has become luminescence thermometry. Herein, we report the structure, luminescence, and temperature detection ability of formate organic–inorganic perovskite [C(NH2)3]M(HCOO)3 (Mg2+, Mn2+, Zn2+) doped with Cr3+ ions. Crystal field strength (Dq/B) and Racah parameters were determined based on diffuse reflectance spectra. It was shown that Cr3+ ions are positioned in the intermediate crystal field or close to it with a Dq/B range of 2.29–2.41. The co-existence of the spin-forbidden and spin-allowed transitions of Cr3+ ions enable the proposal of an approach for remote readout of the temperature. The relative sensitivity (Sr) can be easily modified by sample composition and Cr3+ ions concentration. The luminescent thermometer based on the 2E/4T2g transitions has the relative sensitivity Sr of 2.08%K−1 at 90 K for [C(NH2)3]Mg(HCOO)3: 1% Cr3+ and decrease to 1.20%K−1 at 100 K and 1.08%K−1 at 90 K for Mn2+ and Zn2+ analogs, respectively.
Details
- Language :
- English
- ISSN :
- 14248220
- Volume :
- 23
- Issue :
- 14
- Database :
- Directory of Open Access Journals
- Journal :
- Sensors
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.856619e9df24ce99be6753cdb382097
- Document Type :
- article
- Full Text :
- https://doi.org/10.3390/s23146259