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(2Z)-2-[(2,3-Dimethylphenyl)imino]-1,2-diphenylethanone

Authors :
Muhammad Ilyas Tariq
Muhammad Sarfraz
M. Nawaz Tahir
Shahbaz Ahmad
Ishtiaq Hussain
Source :
Acta Crystallographica Section E, Vol 66, Iss 8, Pp o2078-o2078 (2010)
Publication Year :
2010
Publisher :
International Union of Crystallography, 2010.

Abstract

In the title compound, C22H19NO, the 2,3-dimethylanilinic group is planar with an r.m.s. deviation of 0.0226 Å. The phenyl rings with the carbonyl and imine substituents are also planar with r.m.s. deviations of 0.0019 and 0.0048 Å, respectively. These phenyl rings are oriented at dihedral angles of 74.70 (5) and 79.43 (5)°, respectively, with the 2,3-dimethylanilinic group, whereas the dihedral angle between them is 88.28 (4)°. Weak intramolecular C—H...N hydrogen bonding occurs and completes an S(5) ring motif in the molecule. In the crystal, weak π–π interactions are present between the carbonyl-containing phenyl rings at a centroid–centroid distance of 3.5958 (12) Å. C—H...π interactions between the 2,3-dimethylanilinic and the carbonyl-containing phenyl rings are also present, where the C—H group is from the former.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
66
Issue :
8
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.818a1c61aa324de280953931d12efed4
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536810028217