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N,N′-Dimethyl-N′′-(trichloroacetyl)phosphoramide

Authors :
Vladimir Ovchynnikov
Source :
Acta Crystallographica Section E, Vol 69, Iss 12, Pp o1759-o1759 (2013)
Publication Year :
2013
Publisher :
International Union of Crystallography, 2013.

Abstract

In the title compound, C4H9Cl3N3O2P or CCl3C(O)NHP(O)(NHCH3)2, the P atom has a strongly distorted tetrahedral geometry due to the formation of intermolecular strong hydrogen bonds involving the N atoms. In the crystal, N—H...O=P and N—H...O=C hydrogen bonds connect the molecules into a two-dimensional array parallel to (100). An intramolecular P...O contact [P...O = 2.975 (3) Å] is observed. The CCl3 group is rotationally disordered, with occupancies of 0.60 (3) and 0.40 (3)

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
69
Issue :
12
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.7f58300881744e0eb2bb3b6073eac934
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536813030389