Response Surface Optimization and Floc Structure Analysis of Magnetic Flocculation Technology for Anaerobic Digestion Reject Water

In order to improve the removal efficiencies of SS and Fe3+ in anaerobic digestion reject water for the subsequent biological treatment process, on the basis of the single factor test in the early stage, the response surface method was used, and the structure of the formed floc was analyzed by magnetic flocculation. The optimum amounts of magnetic powder, polyaluminum chloride (PAC) and polyacrylamide (PAM) were 40.51 mg/L, 31.31 mg/L and 4.05 mg/L, respectively. At this time, the removal efficiencies of SS and Fe3+ were 97.84% and 98.35%. The effects of floc particle size, scanning electron microscopy, infrared spectroscopy and two-dimensional fractal dimension of flocs on the flocculation ability showed that: compared with conventional coagulation, the average particle size of flocs treated by magnetic flocculation was 76.56 μm, the Fe-O-Al absorption peak appeared at 984 cm−1, the flocculation ability was significantly improved, the surface of the floc was rough and porous, and the structure was dense, and the sedimentation performance was significantly improved also.