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6-Bromo-3-{2-[2-(diphenylmethylene)hydrazinyl]-1,3-thiazol-5-yl}-2H-chromen-2-one chloroform monosolvate

Authors :
Afsheen Arshad
Hasnah Osman
Chan Kit Lam
Madhukar Hemamalini
Hoong-Kun Fun
Source :
Acta Crystallographica Section E, Vol 67, Iss 5, Pp o1079-o1080 (2011)
Publication Year :
2011
Publisher :
International Union of Crystallography, 2011.

Abstract

In the title compound, C25H16BrN3O2S·CHCl3, the thiazole ring is approximately planar [maximum deviation = 0.002 (3) Å] and makes dihedral angles of 10.75 (14) and 87.75 (15)/2.80 (14)° with the pyran ring system and the two terminal phenyl rings, respectively. The solvent molecule is disordered over two sets of sites, with refined occupancies of 0.639 (7) and 0.361 (7). In the crystal, molecules are connected via pairs of weak C—H...O interactions, forming centrosymmetric dimers. An intramolecular C—H...O hydrogen bond generates an S(6) ring motif.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
67
Issue :
5
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.7534e41a3b0142ff90cee70c92263be1
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536811012335