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Synthesis, physicochemical, optical, thermal and TD-DFT of (E)-N′-((9-ethyl-9H-carbazol-3-yl)-methylene)-4-methyl-benzene-sulfonohydrazide (ECMMBSH): Naked eye and colorimetric Cu2+ ion chemosensor
- Source :
- Journal of King Saud University: Science, Vol 33, Iss 8, Pp 101633- (2021)
- Publication Year :
- 2021
- Publisher :
- Elsevier, 2021.
-
Abstract
- Benzene-sulfonohydrazide (ECMMBSH) Schiff base has been made available in an excellent yield via reflux dehydrate of 4-methylbenzene-sulfonohydrazide with 9-ethyl-9H-carbazole-3-carbaldehyde in EtOH. The synthesis of the ECMMBSH was monitored via two main spectroscopic techniques FT-IR and UV–vis tools; ECMMBSH was characterized via MS, 1H NMR, FT-IR, CHN-EA, TG/DTG, EDX, and UV–vis., analysis. Moreover, DFT-optimized, Molecular Electrostatic Potential (MEP) and MAC/NPA-charge models were performed for ECMMBSH. The HOMO/LUMO and Density of State (DOS) calculated energy levels were compared to Tuac experimental optical energy gap values in methanol. Additionally, the TD-DFT and UV–vis. experimental absorption behavior was matched under the same condition. Moreover, the chemo-sensation effect of the ECMMBSH towered Cu2+ ions via complexation was evaluated by naked eye in addition to the UV–vis spectrophotometric measurements.
- Subjects :
- Copper(II)
NMR
Schiff base
DFT
Sensation
Science (General)
Q1-390
Subjects
Details
- Language :
- English
- ISSN :
- 10183647
- Volume :
- 33
- Issue :
- 8
- Database :
- Directory of Open Access Journals
- Journal :
- Journal of King Saud University: Science
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.750acded496c4763ac57a186802b3784
- Document Type :
- article
- Full Text :
- https://doi.org/10.1016/j.jksus.2021.101633