Back to Search Start Over

Synthesis and crystal structure of 1,3-bis{[N,N-bis(2-hydroxyethyl)amino]methyl}-5-{[(4,6-dimethylpyridin-2-yl)amino]methyl}-2,4,6-triethylbenzene

Authors :
Manuel Stapf
Ute Schmidt
Wilhelm Seichter
Monika Mazik
Source :
Acta Crystallographica Section E: Crystallographic Communications, Vol 78, Iss 8, Pp 825-828 (2022)
Publication Year :
2022
Publisher :
International Union of Crystallography, 2022.

Abstract

In the crystal structure of the title compound, C30H50N4O4, the two bis(hydroxyethyl)amino moieties and the 2,4-dimethylpyridinylamino unit of the molecule are located on one side of the central benzene ring, while the ethyl substituents are oriented in the opposite direction. The dihedral angle between the planes of the aromatic rings is 73.6 (1)°. The conformation of the molecule is stabilized by intramolecular O—H...O (1.86–2.12 Å) and C—H...N (2.40, 2.54 Å) hydrogen bonds. Dimers of inversion-related molecules represent the basic supramolecular entities of the crystal structure. They are further connected via O—H...O hydrogen bonding into undulating layers extending parallel to the crystallographic bc plane. Interlayer interaction is accomplished by weak C—H...π contacts.

Details

Language :
English
ISSN :
20569890
Volume :
78
Issue :
8
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E: Crystallographic Communications
Publication Type :
Academic Journal
Accession number :
edsdoj.7472c7e758ce4696b4828a654dcf397d
Document Type :
article
Full Text :
https://doi.org/10.1107/S2056989022007411