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Synthesis and crystal structure of 1,3-bis{[N,N-bis(2-hydroxyethyl)amino]methyl}-5-{[(4,6-dimethylpyridin-2-yl)amino]methyl}-2,4,6-triethylbenzene
- Source :
- Acta Crystallographica Section E: Crystallographic Communications, Vol 78, Iss 8, Pp 825-828 (2022)
- Publication Year :
- 2022
- Publisher :
- International Union of Crystallography, 2022.
-
Abstract
- In the crystal structure of the title compound, C30H50N4O4, the two bis(hydroxyethyl)amino moieties and the 2,4-dimethylpyridinylamino unit of the molecule are located on one side of the central benzene ring, while the ethyl substituents are oriented in the opposite direction. The dihedral angle between the planes of the aromatic rings is 73.6 (1)°. The conformation of the molecule is stabilized by intramolecular O—H...O (1.86–2.12 Å) and C—H...N (2.40, 2.54 Å) hydrogen bonds. Dimers of inversion-related molecules represent the basic supramolecular entities of the crystal structure. They are further connected via O—H...O hydrogen bonding into undulating layers extending parallel to the crystallographic bc plane. Interlayer interaction is accomplished by weak C—H...π contacts.
Details
- Language :
- English
- ISSN :
- 20569890
- Volume :
- 78
- Issue :
- 8
- Database :
- Directory of Open Access Journals
- Journal :
- Acta Crystallographica Section E: Crystallographic Communications
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.7472c7e758ce4696b4828a654dcf397d
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S2056989022007411