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Oxalatobis(propane-1,3-diamine)manganese(II) chloride monohydrate

Authors :
Qing-Guo Meng
Lin-Tong Wang
Yan-Zhen Liu
Yan Pang
Source :
Acta Crystallographica Section E, Vol 64, Iss 1, Pp m170-m171 (2008)
Publication Year :
2008
Publisher :
International Union of Crystallography, 2008.

Abstract

In the asymmetric unit of the title compound, [Mn(C2O4)(C3H10N2)2]Cl·H2O, there are two independent MnIII complexes, two Cl− anions and two uncoordinated water molecules. Each MnIII atom is hexacoordinated by four N atoms from two propane-1,3-diamine ligands and two O atoms from one oxalate ligand, resulting in a slightly distorted octahedral MnO2N4 geometry. Mn—O and Mn—N bond lengths are in the ranges 1.969 (2)–2.020 (3) and 2.068 (3)–2.113 (4) Å, respectively. There are weak intermolecular O—H...O, O—H...Cl, N—H...O and N—H...Cl hydrogen bonds with D...A distances in the range 2.831 (4)–3.423 (3) Å.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
64
Issue :
1
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.739af51a9dcb4dc6a3da3e6ff0a5ce49
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536807065361