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Crystal structure of tris(trans-1,2-diaminocyclohexane-κ2N,N′)cobalt(III) trichloride monohydrate
- Source :
- Acta Crystallographica Section E: Crystallographic Communications, Vol 72, Iss 1, Pp 49-52 (2016)
- Publication Year :
- 2016
- Publisher :
- International Union of Crystallography, 2016.
-
Abstract
- The synthesis of the title hydrated complex salt, [Co(C6H14N2)3]Cl3·H2O, from racemic trans-1,2-diaminocyclohexane and [CoCl(NH3)5]Cl2 and its structural characterization are presented in this paper. The product was synthesized in the interest of understanding the hydrogen-bonding patterns of coordination complexes. Previous characterizations of the product in the I-42d space group have not yielded coordinates; thus, this paper provides the first coordinates for this complex in this space group. The octahedrally coordinated cation adopts twofold rotation symmetry, with outer-sphere chloride counter-ions and solvent water molecules forming a hydrogen-bonded network with amine H atoms.
Details
- Language :
- English
- ISSN :
- 20569890
- Volume :
- 72
- Issue :
- 1
- Database :
- Directory of Open Access Journals
- Journal :
- Acta Crystallographica Section E: Crystallographic Communications
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.725c607752c648a3acd597e08c5dda4d
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S2056989015023683