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Electrical properties of La3+ and Y3+ ions substituted Ni0.3Cu0.3Zn0.4Fe2O4 nanospinel ferrites

Authors :
M.A. Almessiere
B. Ünal
Y. Slimani
A.D. Korkmaz
A. Baykal
I. Ercan
Source :
Results in Physics, Vol 15, Iss , Pp - (2019)
Publication Year :
2019
Publisher :
Elsevier, 2019.

Abstract

La–Y substituted Ni-Cu-Zn nanospinel ferrites (NSFs) having the following formula Ni0.3Cu0.3Zn0.4LaxYxFe2−2xO4 (x = 0.0–0.10) were fabricated prepared by ultrasonic irradiation approach. The X-ray powder diffractometer (XRD), scanning electron microscope (SEM) and Fourier-transform infrared spectroscopy (FT-IR) were utilized to analyze the structure, vibration bands and morphology. The impedance spectroscopy technique was used for the analysis of electrical and dielectric properties of La3+ and Y3+ ions co-substituted Ni0.3Cu0.3Zn0.4Fe2O4 NSFs. Some important parameters such as ac conductivity, activation energy, dielectric constant and dielectric loss were examined as functions of frequencies and temperatures for a variety of La and Y co-substitution ratios. In general, ac conductivity is observed to fluctuate slightly with the elevated temperatures while its fluctuation level decreases somehow with an increase in co-substitution ratios. Furthermore, the frequency dependence of dielectric functions could be described by Koop's models based on Maxwell-Wagner theory, which elucidates the correlation between the polarizability coefficient and dielectric constant in inhomogeneous double-layer structures. Keywords: Spinel ferrites, Rare earth substitutions, Conductivity, Dielectric properties

Subjects

Subjects :
Physics
QC1-999

Details

Language :
English
ISSN :
22113797
Volume :
15
Issue :
-
Database :
Directory of Open Access Journals
Journal :
Results in Physics
Publication Type :
Academic Journal
Accession number :
edsdoj.71d7d72dc5b749f5ba1eb5618de48b4a
Document Type :
article
Full Text :
https://doi.org/10.1016/j.rinp.2019.102755