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Zwitterionic cellular polymer enabled reductive fixation of CO2 for N-methylation of amines
- Source :
- Green Synthesis and Catalysis, Vol 4, Iss 4, Pp 342-349 (2023)
- Publication Year :
- 2023
- Publisher :
- KeAi Communications Co. Ltd., 2023.
-
Abstract
- Using heterogeneous catalysts to promote the construction of the C–N bond between amines and CO2 under mild conditions is a challenge yet. Herein, we synthesized a novel zwitterionic polymer (PDDC) with a cellular structure via self-complexation of copolymer bearing both quaternary ammonium cation and carboxylate anion. PDDC was employed as a recyclable catalyst for N-methylation of atmospheric CO2 and various amines with hydrosilane as a reductant, affording more than 17 N-methylamines in good to excellent yields (up to 99%) under mild conditions. The behavior of PDDC in the reaction medium was disclosed by using a dynamic light scattering study, revealing that the decreased hydraulic radius of particle size contributes to exposing more active sites and increasing reaction activity. Utilizing a series of designed experiments and density functional theory calculations uncovered the crucial role of the prepared zwitterionic polymer during the reaction procedure of CO2 conversion.
Details
- Language :
- English
- ISSN :
- 26665549
- Volume :
- 4
- Issue :
- 4
- Database :
- Directory of Open Access Journals
- Journal :
- Green Synthesis and Catalysis
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.701d693d0090484084ab2b14ebe9f06c
- Document Type :
- article
- Full Text :
- https://doi.org/10.1016/j.gresc.2023.02.005