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5-Methyl-1-(4-methylphenyl)-N′-[1-(thiophen-2-yl)ethylidene]-1H-1,2,3-triazole-4-carbohydrazide

Authors :
Gamal A. El-Hiti
Bakr F. Abdel-Wahab
Mohammad Hayal Alotaibi
Emad Yousif
Amany S. Hegazy
Benson M. Kariuki
Source :
IUCrData, Vol 3, Iss 10, p x181379 (2018)
Publication Year :
2018
Publisher :
International Union of Crystallography, 2018.

Abstract

The asymmetric unit comprises a single molecule of C17H17N5OS with twist angles between the planes through the thiophenyl, methyltriazolyl and tolyl groups of 12.3 (1) and 44.9 (1)°, respectively. A possible weak intramolecular hydrogen bond forms between the methyl substituent on the triazole ring and the adjacent carbonyl O atom. In the crystal structure, π–π interactions occur between phenyl rings of pairs of molecules related by inversion symmetry with a centroid–centroid separation of 3.7647 (18) Å. The shortest intermolecular hydrogen bonding contact is a C—H...O interaction that generates inversion dimers.

Details

Language :
English
ISSN :
24143146
Volume :
3
Issue :
10
Database :
Directory of Open Access Journals
Journal :
IUCrData
Publication Type :
Academic Journal
Accession number :
edsdoj.6fb4e86f9e9846718c4e5448cc887b96
Document Type :
article
Full Text :
https://doi.org/10.1107/S2414314618013792