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Au-activated N motifs in non-coherent cupric porphyrin metal organic frameworks for promoting and stabilizing ethylene production

Authors :
Xulan Xie
Xiang Zhang
Miao Xie
Likun Xiong
Hao Sun
Yongtao Lu
Qiaoqiao Mu
Mark H. Rummeli
Jiabin Xu
Shuo Li
Jun Zhong
Zhao Deng
Bingyun Ma
Tao Cheng
William A. Goddard
Yang Peng
Source :
Nature Communications, Vol 13, Iss 1, Pp 1-11 (2022)
Publication Year :
2022
Publisher :
Nature Portfolio, 2022.

Abstract

Metal-organic frameworks are promising catalysts for CO2 electroreduction, yet limited by their poor conductivity and stability. Here, Au nanoneedles are inserted into the metalloporphyrin framework to activate C-C coupling and stabilize the structure for much enhanced ethylene production.

Subjects

Subjects :
Science

Details

Language :
English
ISSN :
20411723
Volume :
13
Issue :
1
Database :
Directory of Open Access Journals
Journal :
Nature Communications
Publication Type :
Academic Journal
Accession number :
edsdoj.6c055f08c5f24b88ba951c3a4bfd142d
Document Type :
article
Full Text :
https://doi.org/10.1038/s41467-021-27768-6