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Diaquabis{5-carboxy-2-[(1H-1,2,4-triazol-1-yl)methyl]-1H-imidazole-4-carboxylato}zinc

Authors :
Jing-Hao Hao
Jian-Ling Wang
Source :
Acta Crystallographica Section E, Vol 67, Iss 12, Pp m1645-m1646 (2011)
Publication Year :
2011
Publisher :
International Union of Crystallography, 2011.

Abstract

In the title compound, [Zn(C8H6N5O4)2(H2O)2], the six-coordinate ZnII ion, which is located on an inversion center, has a distorted octahedral configuration. Each 5-carboxy-2-[(1H-1,2,4-triazol-1-yl)methyl]-1H-imidazole-4-carboxylate ligand chelates to the ZnII ion through a triazole N atom and a carboxylate O atom in the equatorial plane. The coordination sphere is completed by two water molecules in axial positions. There is an intramolecular O—H...O hydrogen bond in the ligand. In the crystal, molecules are linked via intermolecular O—H...O, O—H...N and N—H...N hydrogen bonds, forming a three-dimensional structure.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
67
Issue :
12
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.6bc4f343b4a14ebdb1af991178373927
Document Type :
article
Full Text :
https://doi.org/10.1107/S160053681104387X