Back to Search
Start Over
Diaquabis{5-carboxy-2-[(1H-1,2,4-triazol-1-yl)methyl]-1H-imidazole-4-carboxylato}zinc
- Source :
- Acta Crystallographica Section E, Vol 67, Iss 12, Pp m1645-m1646 (2011)
- Publication Year :
- 2011
- Publisher :
- International Union of Crystallography, 2011.
-
Abstract
- In the title compound, [Zn(C8H6N5O4)2(H2O)2], the six-coordinate ZnII ion, which is located on an inversion center, has a distorted octahedral configuration. Each 5-carboxy-2-[(1H-1,2,4-triazol-1-yl)methyl]-1H-imidazole-4-carboxylate ligand chelates to the ZnII ion through a triazole N atom and a carboxylate O atom in the equatorial plane. The coordination sphere is completed by two water molecules in axial positions. There is an intramolecular O—H...O hydrogen bond in the ligand. In the crystal, molecules are linked via intermolecular O—H...O, O—H...N and N—H...N hydrogen bonds, forming a three-dimensional structure.
- Subjects :
- Crystallography
QD901-999
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 67
- Issue :
- 12
- Database :
- Directory of Open Access Journals
- Journal :
- Acta Crystallographica Section E
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.6bc4f343b4a14ebdb1af991178373927
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S160053681104387X