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(1R*,2R*,4S*,5R*,6R*,8S*)-4,8-Dimethyl-2,6-diphenylbicyclo[3.3.1]nonane-2,6-diol

Authors :
Vi T. Nguyen
Roger Bishop
Donald C. Craig
Marcia L. Scudder
Source :
Acta Crystallographica Section E, Vol 65, Iss 4, Pp o886-o886 (2009)
Publication Year :
2009
Publisher :
International Union of Crystallography, 2009.

Abstract

The racemic title compound, C23H28O2, crystallizes in the space group C2/c as a layered structure in which a centrosymmetric three hydrogen bond sequence links four molecules. Both hydroxy groups are involved in this arrangement, but they differ in that one participates in two hydrogen bonds while the other takes part in only one. Between layers, the aromatic rings take part in edge-face interactions [shortest C—H...C distances 3.04, 3.10 and 3.12 Å and angle between normal to planes 86.7(2)°], forming a centrosymmetric dimer. The lattice is further stabilized by C—H...π interactions involving both methyl (shortest C...C 3.82 and 3.97 Å) and methylene (shortest C...C 3.60 Å) groups.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
65
Issue :
4
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.65f64485b6814f8b965db244448e29f8
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536809009933