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Crystal structure of (piperidine-1-carbodithioato-κ2S,S)[2-(pyridin-2-yl)phenyl-κ2C1,N]palladium(II)

Authors :
Mikhail Kondrashov
André Fleckhaus
Roman Gritcenko
Ola F. Wendt
Source :
Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 9, Pp m166-m166 (2015)
Publication Year :
2015
Publisher :
International Union of Crystallography, 2015.

Abstract

The title compound, [Pd(C11H8N)(C6H10NS2)], crystallizes with three similar and discrete molecules in the asymmetric unit. The CNS2 donor set defines a distorted square-planar geometry around the PdII atom, with very small deviations from planarity. The bidentate nature of the ligands gives fairly large deviations from the ideal 90° angles; the C—Pd—N angles are all around 81° and the S—Pd—S angles are around 75°. Molecules pack via dispersion interactions.

Details

Language :
English
ISSN :
20569890
Volume :
71
Issue :
9
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E: Crystallographic Communications
Publication Type :
Academic Journal
Accession number :
edsdoj.642cf9f125384b8787c83deb78b23487
Document Type :
article
Full Text :
https://doi.org/10.1107/S2056989015015005