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An orthorhombic polymorph of cerium(III) ultraphosphate, CeP5O14

Authors :
Jing Zhu
Wen-Dan Cheng
Hao Zhang
Source :
Acta Crystallographica Section E, Vol 64, Iss 11, Pp i74-i74 (2008)
Publication Year :
2008
Publisher :
International Union of Crystallography, 2008.

Abstract

Cerium(III) ultraphosphate, CeP5O14, was synthesized by a high-temperature solution reaction between CeO2 and NH4H2PO4 in a Ce–P molar ratio of 1:12. Colourless crystals of the orthorhombic polymorph were obtained by cooling the melt of the mixture. The structure contains (P5O14)3− anionic ribbons linked by distorted CeO8 polyhedra.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
64
Issue :
11
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.6392c737146b4cb6a185bf6ced4b2f4d
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536808032972