Back to Search
Start Over
Synthesis, crystal structure and Hirshfeld surface analysis of di-μ2-iodido-bis[(2,2′-biquinoline-κ2N,N′)copper(I)]
- Source :
- Acta Crystallographica Section E: Crystallographic Communications, Vol 79, Iss 3, Pp 132-135 (2023)
- Publication Year :
- 2023
- Publisher :
- International Union of Crystallography, 2023.
-
Abstract
- The molecular and crystal structures of the title compound, [Cu2I2(C18H12N2)2], were examined by single-crystal X-ray diffraction and Hirshfeld surface analysis. The Cu atom is coordinated in a distorted tetrahedral geometry by two N atoms from the 2,2′-biquinoline ligands and the two μ2-bridging iodide ligands. The molecules are in contact via π–π-stacking interactions. Hirshfeld surface analysis showed that the most important contributions to the intermolecular interactions are H...H (39.7%), H...I/I...H (17.8%), C...H/H...C (17.5%), C...C (16.5%), N...C/C...N (3.9%) and N...H/H...N (3.5%).
Details
- Language :
- English
- ISSN :
- 20569890
- Volume :
- 79
- Issue :
- 3
- Database :
- Directory of Open Access Journals
- Journal :
- Acta Crystallographica Section E: Crystallographic Communications
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.615e1c8a130444e9b087e46dd0e01650
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S2056989023000634