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S,S′-(Pyridazine-3,6-diyl)dithiouronium dichloride methanol monosolvate
- Source :
- Acta Crystallographica Section E, Vol 67, Iss 6, Pp o1477-o1477 (2011)
- Publication Year :
- 2011
- Publisher :
- International Union of Crystallography, 2011.
-
Abstract
- In the title compound, C6H10N6S22+·2Cl−·CH3OH, the pyridazine ring is almost planar, the greatest deviation from the mean plane being 0.025 (2) Å for one of the ring N atoms. The two thiouronium substituents are tilted out of this plane by 60.87 (6) and 57.94 (7)°. The thiouronium cations and the chloride anions are linked by strong N—H...Cl hydrogen bonds. The methanol solvent molecule interacts with both the chloride ion (through an O—H...Cl hydrogen bond) and the cation (through an N—H...O hydrogen bond), resulting in a three-dimensional supramolecular arrangement.
- Subjects :
- Crystallography
QD901-999
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 67
- Issue :
- 6
- Database :
- Directory of Open Access Journals
- Journal :
- Acta Crystallographica Section E
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.5d9138c9b090472bb1ef9d7a6415a5dd
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S1600536811018514