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S,S′-(Pyridazine-3,6-diyl)dithiouronium dichloride methanol monosolvate

Authors :
Jörg Hübscher
Lidiya Izotova
Samat Talipov
Felix Katzsch
Edwin Weber
Source :
Acta Crystallographica Section E, Vol 67, Iss 6, Pp o1477-o1477 (2011)
Publication Year :
2011
Publisher :
International Union of Crystallography, 2011.

Abstract

In the title compound, C6H10N6S22+·2Cl−·CH3OH, the pyridazine ring is almost planar, the greatest deviation from the mean plane being 0.025 (2) Å for one of the ring N atoms. The two thiouronium substituents are tilted out of this plane by 60.87 (6) and 57.94 (7)°. The thiouronium cations and the chloride anions are linked by strong N—H...Cl hydrogen bonds. The methanol solvent molecule interacts with both the chloride ion (through an O—H...Cl hydrogen bond) and the cation (through an N—H...O hydrogen bond), resulting in a three-dimensional supramolecular arrangement.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
67
Issue :
6
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.5d9138c9b090472bb1ef9d7a6415a5dd
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536811018514