Back to Search Start Over

SYNTHESIS, CRYSTAL STRUCTURE, AND PROPERTIES OF COPPER(II) COMPLEXES WITH 1,4,7-TRIS(2-AMINOETHYL)-1,4,7-TRIAZACYCLONONANE

Authors :
Masahiro Mikuriya
Mayu Hamagawa
Natsuki Tomioka
Daisuke Yoshioka
Naoko Uehara
Rika Fujimori
Hiroki Yamamoto
Yoshinari Ando
Shoichi Hori
Taro Kuriyama
Ryoji Mitsuhashi
Makoto Handa
Source :
Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry, Vol 10, Iss 2, Pp 40-47 (2015)
Publication Year :
2015
Publisher :
Academy of Sciences of Moldova, Institute of Chemistry, 2015.

Abstract

Three kinds of copper(II) complexes with 1,4,7-tris(2-aminoethyl)-1,4,7-triazacyclononane (taetacn), [Cu(taetacn)](ClO4)2 (1), [Cu(Htaetacn)](ClO4)3 (2), and [Cu(Htaetacn)](BF4)3 (3) were synthesized and characterized by elemental analyses, IR and UV-Vis spectroscopies. The spectral features are in harmony with an octahedral geometry for 1 and a square-pyramidal coordination for 2 and 3.

Details

Language :
English
ISSN :
18571727 and 23451688
Volume :
10
Issue :
2
Database :
Directory of Open Access Journals
Journal :
Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry
Publication Type :
Academic Journal
Accession number :
edsdoj.5b5c13866f194ad3ae9d4be8307ca995
Document Type :
article