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Aquabis(triphenylphosphine-κP)copper(I) tetrafluoridoborate

Authors :
Yanfeng Dai
Yi Zhang
Jianwen Tian
Zhen Liu
Source :
Acta Crystallographica Section E, Vol 65, Iss 8, Pp m1001-m1001 (2009)
Publication Year :
2009
Publisher :
International Union of Crystallography, 2009.

Abstract

In the title compound, [Cu(C18H15P)2(H2O)]BF4, the CuI atom is coordinated by two P atoms from triphenylphosphine ligands and one water molecule in a distorted trigonal geometry. In the BF4− anion, three F atoms are disordered over two sites around the B—F bond, the site-occupancy ratio being 0.67 (6):0.33 (6). The Cu...F distance of 2.602 (5) Å between the Cu atom and the ordered F atom may suggest a weak but genuine interaction. O—H...F and weak C—H...F hydrogen bonding is present in the crystal structure.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
65
Issue :
8
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.59d4813181054598a0ccdc12ca32089d
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536809029559