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Aquabis(triphenylphosphine-κP)copper(I) tetrafluoridoborate
- Source :
- Acta Crystallographica Section E, Vol 65, Iss 8, Pp m1001-m1001 (2009)
- Publication Year :
- 2009
- Publisher :
- International Union of Crystallography, 2009.
-
Abstract
- In the title compound, [Cu(C18H15P)2(H2O)]BF4, the CuI atom is coordinated by two P atoms from triphenylphosphine ligands and one water molecule in a distorted trigonal geometry. In the BF4− anion, three F atoms are disordered over two sites around the B—F bond, the site-occupancy ratio being 0.67 (6):0.33 (6). The Cu...F distance of 2.602 (5) Å between the Cu atom and the ordered F atom may suggest a weak but genuine interaction. O—H...F and weak C—H...F hydrogen bonding is present in the crystal structure.
- Subjects :
- Crystallography
QD901-999
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 65
- Issue :
- 8
- Database :
- Directory of Open Access Journals
- Journal :
- Acta Crystallographica Section E
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.59d4813181054598a0ccdc12ca32089d
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S1600536809029559