CO2 Liquefaction Close to the Triple Point Pressure

For vessel-based transport of liquid CO2 in carbon capture and storage chains, transport at 8 bar(a) enable significant cost reductions compared to transport at higher pressures for most transport distances and volumes. Transport at even lower pressures could further reduce the costs. There are, however, concerns related to dry ice formation and potential clogging in parts of the chain that could lead to operational issues when operating close to the triple point pressure of CO2. In this paper, results from an experimental campaign to de-risk and gain operational experience from the low-pressure CO2 liquefaction process are described. Six experiments using pure CO2 or CO2/N2 mixtures are presented. In four of the experiments, the liquid product pressure was continuously lowered until dry ice was detected and eventually clogged the system. In the final two experiments, the liquefaction process was run in steady-state at low liquefaction pressures for five hours to ensure that there is no undetected dry ice in the process that could lead to accumulation and operational issues over time. These experiments demonstrate that pure CO2 can be safely liquefied at 5.8 bar(a) and a CO2/N2 mixture can be liquefied at 6.5 bar(a) without issues related to dry ice formation.