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HKUST-1@IL-Li Solid-state Electrolyte with 3D Ionic Channels and Enhanced Fast Li+ Transport for Lithium Metal Batteries at High Temperature
- Source :
- Nanomaterials, Vol 11, Iss 3, p 736 (2021)
- Publication Year :
- 2021
- Publisher :
- MDPI AG, 2021.
-
Abstract
- The challenge of safety problems in lithium batteries caused by conventional electrolytes at high temperatures is addressed in this study. A novel solid electrolyte (HKUST-1@IL-Li) was fabricated by immobilizing ionic liquid ([EMIM][TFSI]) in the nanopores of a HKUST-1 metal–organic framework. 3D angstrom-level ionic channels of the metal–organic framework (MOF) host were used to restrict electrolyte anions and acted as “highways” for fast Li+ transport. In addition, lower interfacial resistance between HKUST-1@IL-Li and electrodes was achieved by a wetted contact through open tunnels at the atomic scale. Excellent high thermal stability up to 300 °C and electrochemical properties are observed, including ionic conductivities and Li+ transference numbers of 0.68 × 10−4 S·cm−1 and 0.46, respectively, at 25 °C, and 6.85 × 10−4 S·cm−1 and 0.68, respectively, at 100 °C. A stable Li metal plating/stripping process was observed at 100 °C, suggesting an effectively suppressed growth of Li dendrites. The as-fabricated LiFePO4/HKUST-1@IL-Li/Li solid-state battery exhibits remarkable performance at high temperature with an initial discharge capacity of 144 mAh·g−1 at 0.5 C and a high capacity retention of 92% after 100 cycles. Thus, the solid electrolyte in this study demonstrates promising applicability in lithium metal batteries with high performance under extreme thermal environmental conditions.
Details
- Language :
- English
- ISSN :
- 20794991
- Volume :
- 11
- Issue :
- 3
- Database :
- Directory of Open Access Journals
- Journal :
- Nanomaterials
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.58efff0bf0644456aa7aa15482e2cd2c
- Document Type :
- article
- Full Text :
- https://doi.org/10.3390/nano11030736