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(2,2′-Bipyridine-κ2N,N′)bis(nitrato-κ2O,O′)copper(II)

Authors :
Feng-Yi Liu
Ming-Hui Zhang
Jun-Feng Kou
Source :
Acta Crystallographica Section E, Vol 69, Iss 11, Pp m609-m609 (2013)
Publication Year :
2013
Publisher :
International Union of Crystallography, 2013.

Abstract

In the title complex, [Cu(NO3)2(C10H8N2)], the CuII cation is chelated by two nitrate anions and by one 2,2′-bipyridine ligand in a distorted N2O4 octahedral geometry. The dihedral angle between the pyridine rings is 1.92 (11)°. In the crystal, π–π stacking between parallel pyridine rings of adjacent complex molecules is observed, the centroid–centroid distance being 3.6788 (19) Å. Weak C—H...O hydrogen bonds further link the molecules into a three-dimensional supramolecular architecture.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
69
Issue :
11
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.56fa1b61726c4d45a4d4dbe425c8c161
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536813028201