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Geochemical and thermal characterization and kinetics of oil shale samples from Çeltek, Türkiye

Authors :
Mustafa Verşan Kök
Source :
Oil Shale, Vol 41, Iss 2, Pp 103-114 (2024)
Publication Year :
2024
Publisher :
Estonian Academy Publishers, 2024.

Abstract

This research delves into the geochemical aspects, non-isothermal thermogravimetric analysis, and model-free kinetics of oil shale samples from the Ãeltek region in Amasya, Türkiye. Shifting the focus to the core of the research, thermal and mass spectrometric analysis (TGâDTGâMS) experiments were conducted in an air atmosphere, employing three distinct heating rates of 10, 20, and 30 °C/min. The outcomes revealed two successive reaction stages: the breakdown of organic matter and mineral decomposition. In the breakdown stage, activation energy values exhibited a range of 160â163 kJ/mol, while in the mineral decomposition stage, the values varied between 208â214 kJ/mol, using model-free kinetic models.

Details

Language :
English
ISSN :
0208189X and 17367492
Volume :
41
Issue :
2
Database :
Directory of Open Access Journals
Journal :
Oil Shale
Publication Type :
Academic Journal
Accession number :
edsdoj.53cf3d1733df4555b291b625321ae2c6
Document Type :
article
Full Text :
https://doi.org/10.3176/oil.2024.2.02