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An Application of Safety Assessment for Radioactive Waste Repository: Non-Equilibrium Transport of Tritium, Selenium, and Cesium in Crushed Granite with Different Path Lengths

Authors :
Chuan-Pin Lee
Dongyang Chen
Yanqin Hu
Yi-Lin Jan
Yunfeng Shi
Ziteng Wang
Enhui Wu
Neng-Chuan Tien
Yuzhen Sun
Shih-Chin Tsai
Source :
Applied Sciences, Vol 11, Iss 20, p 9750 (2021)
Publication Year :
2021
Publisher :
MDPI AG, 2021.

Abstract

Advection-dispersion experiments (ADE) were effectively designed for inadequate transport models through a calibration/validation process. HTO, selenium (Se), and cesium (Cs) transport in crushed granite were studied using a highly reliable, dynamic column device in order to obtain the retardation factors (R) and the dispersion coefficients (D) by fitting experimental breakthrough curves (BTCs) for various path lengths. In order to conduct a safety assessment (SA) of a deep geological repository for high-level radioactive waste, radionuclide transport in rock systems is necessary to clarify and establish a suitable model. A dynamic column with a radiotracer (HTO, Se(IV), and Cs) was applied to 2, 4, and 8 cm path lengths using a STANMOD simulation. The results showed similar results between the BTCs of Se and Cs by fitting a non-equilibrium sorption model due to the retardation effect. In fact, there was a relatively obvious sorption of Se and Cs in the BTCs obtained by fitting a retardation factor (R) value higher than 1. In addition, a two-region (physical) and a two-site (chemical) non-equilibrium model with either the lowest sum of squared residuals (SSQ) or the root mean square error (RMSE) were applied to determine the Se and Cs sorption mechanisms on granite.

Details

Language :
English
ISSN :
20763417
Volume :
11
Issue :
20
Database :
Directory of Open Access Journals
Journal :
Applied Sciences
Publication Type :
Academic Journal
Accession number :
edsdoj.4f95eae169e4aa1ae8d2bb87cd32347
Document Type :
article
Full Text :
https://doi.org/10.3390/app11209750