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(2,7-Dimethoxynaphthalen-1-yl)(3-nitrophenyl)methanone

Authors :
Kotaro Kataoka
Takahiro Nishijima
Atsushi Nagasawa
Akiko Okamoto
Noriyuki Yonezawa
Source :
Acta Crystallographica Section E, Vol 66, Iss 11, Pp o2972-o2972 (2010)
Publication Year :
2010
Publisher :
International Union of Crystallography, 2010.

Abstract

The title compound, C19H15NO5, has an intramolecular C—H...O=C hydrogen bond between a naphthalene H atom and the O atom of the carbonyl group. The interplanar angle between the naphthalene ring system and the benzene ring is 69.59 (5)°. The dihedral angle between the bridging carbonyl C—C(=O)—C plane and the naphthalene ring system is 61.02 (6)°, which is far larger than that between the bridging carbonyl plane and the benzene ring [12.68 (7)°]. The nitro group is slightly out of the plane of the benzene ring [O—N—C—C torsion angle = 4.97 (17)°]. In the crystal, the packing is mainly stabilized by C—H...O interactions between an H atom of the benzene ring and an O atom of the nitro group.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
66
Issue :
11
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.4ee35b24d280457a9727bfa9b97f2300
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536810042819