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Environmental Remediation of Metribuzin Herbicide by Mesoporous Carbon—Rich from Wheat Straw

Authors :
Irina Gabriela Cara
Manuela Filip
Laura Bulgariu
Lucian Raus
Denis Topa
Gerard Jitareanu
Source :
Applied Sciences, Vol 11, Iss 11, p 4935 (2021)
Publication Year :
2021
Publisher :
MDPI AG, 2021.

Abstract

Contemporary farming practices and rapid industrialization over the last few decades, have raised significant soil and water pollution with extreme toxic effects to humans and ecosystems. The widespread and inefficient use of pesticides, which surpass the soil’s self purification capability, has accelerated soil pollution. In this study, wheat straw biochar was obtained using the traditional pyrolysis technique and its characterization; in addition, the adsorption efficiency of metribuzin was investigated. Biochars’ physical and chemical characteristics were qualified using scanning electron microscopy and Fourier transform infrared spectroscopy. A batch sorption test and liquid chromatography coupled with mass spectrometry were also used to assess the biochar efficiency. SEM and FTIR confirmed the highly reactive surfaces of biochar, establishing efficient biomass conversion in low-oxygen conditions. The adsorption process showed best fit with pseudo second-order kinetic and Langmuir models, suggesting a chemisorption procedure and monolayer-type removal. Regarding its environmental and agricultural application, wheat straw biochar can be advanced as a recommendation solution for further research, which is fundamental for soil rehabilitation and the immobilization of contaminations.

Details

Language :
English
ISSN :
20763417
Volume :
11
Issue :
11
Database :
Directory of Open Access Journals
Journal :
Applied Sciences
Publication Type :
Academic Journal
Accession number :
edsdoj.499644dbe4404177b5cdbd591ae87a12
Document Type :
article
Full Text :
https://doi.org/10.3390/app11114935