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(+)-(1S,5R,10S)-11,11-Dimethyl-4-oxatricyclo[8.4.0.01,5]tetradecane-3,12-dione
- Source :
- Acta Crystallographica Section E, Vol 64, Iss 1, Pp o287-o287 (2008)
- Publication Year :
- 2008
- Publisher :
- International Union of Crystallography, 2008.
-
Abstract
- The title compound, C15H22O3, was prepared via amino-acid-promoted Robinson annulation followed by tandem Pd/C-mediated hydrogenation and oxidative cyclization. This product was instrumental in determining the feasibility of a stereocontrolled hydrogenation in which the directing hydroxyl group is adjacent to the 6–7-ring network and its olefinic component. The asymmetric unit consists of a single molecule with normal geometric parameters. The absolute configuration was assigned based on the known enantiomeric prescursor. Intermolecular C—H...O interactions link each molecule with four neighboring molecules.
- Subjects :
- Crystallography
QD901-999
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 64
- Issue :
- 1
- Database :
- Directory of Open Access Journals
- Journal :
- Acta Crystallographica Section E
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.48c6da5208d4a8283805d640959477f
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S1600536807066159