Back to Search Start Over

{(Hydrogen 2,2′,2′′-boranetriyl)tris[6-tert-butyl-4-methylpyridazine-3(2H)-thione]-κ3H,S,S′}(triphenylphosphane-κP)copper(I) chloroform disolvate

Authors :
Stefan Holler
Ferdinand Belaj
Nadia C. Mösch-Zanetti
Source :
IUCrData, Vol 2, Iss 12, p x171772 (2017)
Publication Year :
2017
Publisher :
International Union of Crystallography, 2017.

Abstract

In the title complex, [Cu(C27H40BN6S3)(C18H15P)]·2CHCl3, the CuI atom is surrounded in a trigonal-planar arrangement by the triphenylphosphane ligand and two of the three S atoms of the scorpionate ligand with an additional 3-center–2-electron B—H...Cu interaction, with the H atom as the apex of a pyramid [B—H = 1.140 (17) Å and Cu—H = 1.826 (16) Å].

Details

Language :
English
ISSN :
24143146
Volume :
2
Issue :
12
Database :
Directory of Open Access Journals
Journal :
IUCrData
Publication Type :
Academic Journal
Accession number :
edsdoj.4508f172bfc41fbb93a002088be7dbd
Document Type :
article
Full Text :
https://doi.org/10.1107/S2414314617017722