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{(Hydrogen 2,2′,2′′-boranetriyl)tris[6-tert-butyl-4-methylpyridazine-3(2H)-thione]-κ3H,S,S′}(triphenylphosphane-κP)copper(I) chloroform disolvate
- Source :
- IUCrData, Vol 2, Iss 12, p x171772 (2017)
- Publication Year :
- 2017
- Publisher :
- International Union of Crystallography, 2017.
-
Abstract
- In the title complex, [Cu(C27H40BN6S3)(C18H15P)]·2CHCl3, the CuI atom is surrounded in a trigonal-planar arrangement by the triphenylphosphane ligand and two of the three S atoms of the scorpionate ligand with an additional 3-center–2-electron B—H...Cu interaction, with the H atom as the apex of a pyramid [B—H = 1.140 (17) Å and Cu—H = 1.826 (16) Å].
- Subjects :
- crystal structure
scorpionate ligand
copper complex
Crystallography
QD901-999
Subjects
Details
- Language :
- English
- ISSN :
- 24143146
- Volume :
- 2
- Issue :
- 12
- Database :
- Directory of Open Access Journals
- Journal :
- IUCrData
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.4508f172bfc41fbb93a002088be7dbd
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S2414314617017722