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Crystal structure and Hirshfeld surface analysis of 2-(4-bromophenyl)-4-methyl-6-oxo-1-phenyl-1,6-dihydropyridine-3-carbonitrile

Authors :
Farid N. Naghiyev
Victor N. Khrustalev
Ekaterina V. Dobrokhotova
Mehmet Akkurt
Ali N. Khalilov
Ajaya Bhattarai
İbrahim G. Mamedov
Source :
Acta Crystallographica Section E: Crystallographic Communications, Vol 78, Iss 8, Pp 761-765 (2022)
Publication Year :
2022
Publisher :
International Union of Crystallography, 2022.

Abstract

In the title compound, C19H13BrN2O, the pyridine ring is essentially planar [maximum deviation = 0.024 (4) Å for the N atom] and makes dihedral angles of 74.6 (2) and 65.8 (2)°, respectively, with the phenyl and bromophenyl rings, which subtend a dihedral angle of 63.1 (2)°. In the crystal, molecules are connected along the c-axis direction via C—Br...π interactions, generating zigzag chains parallel to the (010) plane. C—H...N and C—H...O hydrogen-bonding interactions further connect the molecules, forming a three-dimensional network and reinforcing the molecular packing. Hirshfeld surface analysis indicates that the most important contributions to the crystal packing are from H...H (36.2%), C...H/H...C (21.6%), N...H/H...N (12.2%), and Br...H/H...Br (10.8%) interactions.

Details

Language :
English
ISSN :
20569890
Volume :
78
Issue :
8
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E: Crystallographic Communications
Publication Type :
Academic Journal
Accession number :
edsdoj.425c21b1f6e54c20aa634f9aa8f64de3
Document Type :
article
Full Text :
https://doi.org/10.1107/S2056989022006466