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Crystal structure and Hirshfeld surface analysis of 2-(4-bromophenyl)-4-methyl-6-oxo-1-phenyl-1,6-dihydropyridine-3-carbonitrile
- Source :
- Acta Crystallographica Section E: Crystallographic Communications, Vol 78, Iss 8, Pp 761-765 (2022)
- Publication Year :
- 2022
- Publisher :
- International Union of Crystallography, 2022.
-
Abstract
- In the title compound, C19H13BrN2O, the pyridine ring is essentially planar [maximum deviation = 0.024 (4) Å for the N atom] and makes dihedral angles of 74.6 (2) and 65.8 (2)°, respectively, with the phenyl and bromophenyl rings, which subtend a dihedral angle of 63.1 (2)°. In the crystal, molecules are connected along the c-axis direction via C—Br...π interactions, generating zigzag chains parallel to the (010) plane. C—H...N and C—H...O hydrogen-bonding interactions further connect the molecules, forming a three-dimensional network and reinforcing the molecular packing. Hirshfeld surface analysis indicates that the most important contributions to the crystal packing are from H...H (36.2%), C...H/H...C (21.6%), N...H/H...N (12.2%), and Br...H/H...Br (10.8%) interactions.
Details
- Language :
- English
- ISSN :
- 20569890
- Volume :
- 78
- Issue :
- 8
- Database :
- Directory of Open Access Journals
- Journal :
- Acta Crystallographica Section E: Crystallographic Communications
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.425c21b1f6e54c20aa634f9aa8f64de3
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S2056989022006466