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In situ redox reactions facilitate the assembly of a mixed-valence metal-organic nanocapsule

Authors :
Asanka S. Rathnayake
Hector W. L. Fraser
Euan K. Brechin
Scott J. Dalgarno
Jakob E. Baumeister
Joshua White
Pokpong Rungthanaphatsophon
Justin R. Walensky
Charles L. Barnes
Simon J. Teat
Jerry L. Atwood
Source :
Nature Communications, Vol 9, Iss 1, Pp 1-6 (2018)
Publication Year :
2018
Publisher :
Nature Portfolio, 2018.

Abstract

New approaches are required to access metal-organic assemblies with unusual structural properties. Here, the authors use an in situ redox reaction to obtain a mixed-valence, Mn(II)/Mn(III)-containing metal-organic nanocapsule with an odd number of metal ions.

Subjects

Subjects :
Science

Details

Language :
English
ISSN :
20411723
Volume :
9
Issue :
1
Database :
Directory of Open Access Journals
Journal :
Nature Communications
Publication Type :
Academic Journal
Accession number :
edsdoj.415c36e3c1664396953d80934f3dae4f
Document Type :
article
Full Text :
https://doi.org/10.1038/s41467-018-04541-w