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Removing Basic Fuchsine Dye by Adsorption over CuCo2O4 Nanocomposite as an Active Adsorbent Surface

Authors :
Ali A. Kadhim
Muneer A. Al-Da’amy
Salah H. Kadhim
Eman Talib Kareem
Source :
Baghdad Science Journal, Vol 21, Iss 7 (2024)
Publication Year :
2024
Publisher :
College of Science for Women, University of Baghdad, 2024.

Abstract

This study involves the synthesis of CuCo2O4 spinel-type nanocomposite. This material was synthesized using the co-precipitation method and characterized by Fourier Transform Infrared Spectroscopy (FTIR), X-rays Diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM), and Atomic Force Microscopy (AFM). The activity of the synthesized materials was investigated by following removing basic fuchsine (BF) dye from its aqueous solution by adsorption. Different adsorption parameters were conducted involving the dose of adsorbent surface, time of adsorption, pH of the medium, and temperature. The optimum removal efficiency was around 97 % at contact time 5 minutes, 0.005g of dose the surface adsorbent, pH = 8 and 50 mg. L-1 concentration of dye. Thermodynamic parameters for the adsorption of this dye over the prepared materials were also conducted such as free energy (∆G) negative. While enthalpy (∆H) positive which indicates the adsorption was spontaneous and endothermic, also entropy (∆S) was positive shows the affinity of the adsorbent towards the adsorbate.

Details

Language :
Arabic, English
ISSN :
20788665 and 24117986
Volume :
21
Issue :
7
Database :
Directory of Open Access Journals
Journal :
Baghdad Science Journal
Publication Type :
Academic Journal
Accession number :
edsdoj.412720400c53427393ff8595cf80fc55
Document Type :
article
Full Text :
https://doi.org/10.21123/bsj.2023.8782