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Dissolution and regeneration of lignocellulosic materials with ionic liquids BMIMCl and ([BMIM] [MeSO4]) and determination some of mechanical and physical properties

Authors :
Ebrahim H.Marvdast
Ali Abdolkhani
A.Naghi Karimi
Yahya Hamzeh
Source :
Iranian Journal of Wood and Paper Industries, Vol 4, Iss 1, Pp 117-130 (2012)
Publication Year :
2012
Publisher :
Iranian Scientific Association of Wood and Paper Industries, 2012.

Abstract

In this study two imidazole-based Ionic liquids, 1- butyl -3 - methyl -1 - Imidazolium chloride (BMIMCl) and 1- butyl -3 - Methyl Imidazolium Methyl sulfate ([BMIM][MeSo4]), were used to dissolve wood flour, cellulose and CMP pulp. The overall evaluation indicates the inability of ([BMIM][MeSo4]) in full dissolution of lignocellulosic materials and sample treatment with this solvent was lead to water soluble degradation products. However, dissolution trials using BMIMCl was able to dissolve Lignocellulosics. Density, clarity, water absorption and thickness swelling of regenerated cellulose films were significantly higher than that of CMP and wood flour, and CMP, higher than wood flour. Also, cellulose film have the lowest water vapor permeability compared to wood flour and CMP. Tensile strength, Young's modulus and strain at breaking point of cellulose film were significantly higher than the CMP and wood flour samples.

Details

Language :
Persian
ISSN :
20089066 and 24233242
Volume :
4
Issue :
1
Database :
Directory of Open Access Journals
Journal :
Iranian Journal of Wood and Paper Industries
Publication Type :
Academic Journal
Accession number :
edsdoj.4070e277858d469a96c73231d85dad4e
Document Type :
article