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Chloridobis(1,10-phenanthroline-κ2N,N′)copper(I) dichloridocopper(II)
- Source :
- Acta Crystallographica Section E, Vol 67, Iss 2, Pp m226-m226 (2011)
- Publication Year :
- 2011
- Publisher :
- International Union of Crystallography, 2011.
-
Abstract
- The asymmetric unit of the title compound, [CuCl(C12H8N2)2]·[CuCl2], contains two complex Cu(II) cations and two cuprate(I) anions. The Cu(II) atom is coordinated by two phenanthroline (phen) molecules and one chloride anion in a distorted trigonal–bipyramidal geometry. The Cu(II) complex cations form layers through π–π stacking [interplanar distance = 3.481 (2) Å]. The dichloridocuprate(I) anions are located between the layers, forming a sandwich-like structure.
- Subjects :
- Crystallography
QD901-999
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 67
- Issue :
- 2
- Database :
- Directory of Open Access Journals
- Journal :
- Acta Crystallographica Section E
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.3f5c88bb422144459fef0e674b444281
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S1600536810054073