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[N,N′-Bis(2,3,4-trimethoxybenzylidene)ethane-1,2-diamine-κ2N,N′]dibromidomercury(II)

Authors :
Aliakbar Dehno Khalaji
Michal Dušek
Karla Fejfarová
Source :
Acta Crystallographica Section E, Vol 68, Iss 8, Pp m1044-m1044 (2012)
Publication Year :
2012
Publisher :
International Union of Crystallography, 2012.

Abstract

In the title compound, [HgBr2(C22H28N2O6)], the HgII ion is bonded to two Br− ions and two N atoms of the chelating Schiff base ligand in a distorted tetrahedral geometry. The Schiff base ligand adopts an E,E conformation. The dihedral angle between the planes of the two halves of the central N,N′-dimethylethylenediamine part of the ligand is 2.3 (11)°. The crystal studied was twinned by pseudomerohedry [twin law (0-10/-100/00-1)]; the contribution of the minor twin component refined to 0.208 (3).

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
68
Issue :
8
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.39e7e735d3054650926d213bb85214b5
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536812030577