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Nickel hexayttrium decaiodide, [NiY6]I10
- Source :
- Acta Crystallographica Section E, Vol 70, Iss 6, Pp i26-i26 (2014)
- Publication Year :
- 2014
- Publisher :
- International Union of Crystallography, 2014.
-
Abstract
- Comproportionation reactions of yttrium triiodide, yttrium and nickel led to the formation of the compound [NiY6]I10, which is isostructural with the prototypical [RuY6]I10. In particular, [NiY6]I10 is composed of isolated nickel centered yttrium octahedra (site symmetry -1) that are further surrounded by iodide ligands to construct a three-dimensional cluster complex framework. Although this compound has been previously detected by powder X-ray diffraction techniques [Payne & Corbett (1990). Inorg. Chem. 29, 2246–2251], details of the crystal structure for triclinic [NiY6]I10 were not provided.
- Subjects :
- Crystallography
QD901-999
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 70
- Issue :
- 6
- Database :
- Directory of Open Access Journals
- Journal :
- Acta Crystallographica Section E
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.34e33866739c44749d69eafc52158eaf
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S1600536814009775