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Catalytic transformation of dinitrogen into ammonia and hydrazine by iron-dinitrogen complexes bearing pincer ligand

Authors :
Shogo Kuriyama
Kazuya Arashiba
Kazunari Nakajima
Yuki Matsuo
Hiromasa Tanaka
Kazuyuki Ishii
Kazunari Yoshizawa
Yoshiaki Nishibayashi
Source :
Nature Communications, Vol 7, Iss 1, Pp 1-9 (2016)
Publication Year :
2016
Publisher :
Nature Portfolio, 2016.

Abstract

Converting dinitrogen into other nitrogen compounds such as ammonia is a difficult task, especially under mild conditions. Here, the authors report a molecular iron complex capable of reducing dinitrogen to both ammonia and hydrazine in a catalytic process.

Subjects

Subjects :
Science

Details

Language :
English
ISSN :
20411723
Volume :
7
Issue :
1
Database :
Directory of Open Access Journals
Journal :
Nature Communications
Publication Type :
Academic Journal
Accession number :
edsdoj.33ba2d98c375476682dbd60b29a2b752
Document Type :
article
Full Text :
https://doi.org/10.1038/ncomms12181