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trans-Bis[1,2-bis(diphenylphosphanyl)ethane]chlorido(ethynyl)ruthenium(II)
- Source :
- Acta Crystallographica Section E, Vol 68, Iss 12, Pp m1445-m1445 (2012)
- Publication Year :
- 2012
- Publisher :
- International Union of Crystallography, 2012.
-
Abstract
- The molecular structure of the title compound, trans-[Cu(C2H)Cl(C26H24P2)2], consists of an RuII cation, located on an inversion centre, in an octahedral environment defined by two chelating phosphines, one acetylide and one chloride ligand. The –C[triple-bond]CH and the chlorine ligands are disordered over two equivalent positions (0.5 occupancy each). The coordination geometry is distorted octahedral, with the –C[triple-bond]CH fragment and the Cl ligand in trans positions. The four P atoms occupy the equatorial plane of the octahedron and the chloride and acetylide ligands the axial positions.
- Subjects :
- Crystallography
QD901-999
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 68
- Issue :
- 12
- Database :
- Directory of Open Access Journals
- Journal :
- Acta Crystallographica Section E
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.327bde6b3ae4749aef2138315064567
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S1600536812044558