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trans-Bis[1,2-bis(diphenylphosphanyl)ethane]chlorido(ethynyl)ruthenium(II)

Authors :
Alexander Trujillo
Mauricio Fuentealba
Ramiro Arratia-Perez
Judith A. K. Howard
Source :
Acta Crystallographica Section E, Vol 68, Iss 12, Pp m1445-m1445 (2012)
Publication Year :
2012
Publisher :
International Union of Crystallography, 2012.

Abstract

The molecular structure of the title compound, trans-[Cu(C2H)Cl(C26H24P2)2], consists of an RuII cation, located on an inversion centre, in an octahedral environment defined by two chelating phosphines, one acetylide and one chloride ligand. The –C[triple-bond]CH and the chlorine ligands are disordered over two equivalent positions (0.5 occupancy each). The coordination geometry is distorted octahedral, with the –C[triple-bond]CH fragment and the Cl ligand in trans positions. The four P atoms occupy the equatorial plane of the octahedron and the chloride and acetylide ligands the axial positions.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
68
Issue :
12
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.327bde6b3ae4749aef2138315064567
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536812044558