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(1-Adamantyl)(4-aminophenyl)methanol

Authors :
Marek Nečas
Michal Rouchal
Robert Vícha
Source :
Acta Crystallographica Section E, Vol 65, Iss 5, Pp o1018-o1018 (2009)
Publication Year :
2009
Publisher :
International Union of Crystallography, 2009.

Abstract

In the racemic crystal of the title compound, C17H23NO, enantiomers of the two crystallographically independent molecules are linked into face-to-face RSdimers via intermolecular O—H...N hydrogen bonds and π–π interactions with centroid–centroid distances of 3.7610 (2) Å. The molecules adopt slightly different conformations and contain an adamantane cage consisting of three fused cyclohexane rings in almost ideal chair conformations, with C—C—C angles varying within the range 107.2 (4)–111.4 (4)°. In the hydrogen-bonded pair, the benzene rings are almost coplanar, the dihedral angle between them being 1.29 (13)°. The molecular packing in the crystal is stabilized by additional intermolecular N—H...O hydrogen bonds.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
65
Issue :
5
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.2f407646e634ba899461680a1d678d1
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536809012987