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Deactivation of Partially (dis)Charged LNMO in Contact with Water by Electrochemical Protonation of Li(1 − x)Ni0.5Mn1.5O4
- Source :
- Advanced Materials Interfaces, Vol 11, Iss 16, Pp n/a-n/a (2024)
- Publication Year :
- 2024
- Publisher :
- Wiley-VCH, 2024.
-
Abstract
- Abstract The development of water‐based composite cathode slurries for Li‐ion batteries is hindered by adverse interactions between the battery active material and water. Insights into interactions between H2O and LiNi0.5Mn1.5O4 (LNMO) are studied using a thin‐film model system. The reactivity of this active material with H2O is evaluated at different lithiation states, showing that protonation of the active material in aqueous environments is electrochemically driven, rather than a chemical Li+/H+ ion exchange reaction. The electrochemically driven mechanism describing the protonation of LNMO is only present when the material is in its partially delithiated form. These findings suggest it is possible to cast this material from an aqueous precursor when lithiated, as long as there are no traces of it when the electrochemical delithiation (cell charging) is carried out.
- Subjects :
- cathode
Li‐ion
LNMO
proton exchange
water
Physics
QC1-999
Technology
Subjects
Details
- Language :
- English
- ISSN :
- 21967350
- Volume :
- 11
- Issue :
- 16
- Database :
- Directory of Open Access Journals
- Journal :
- Advanced Materials Interfaces
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.2e2cce26f08a41be808f36bb07474f17
- Document Type :
- article
- Full Text :
- https://doi.org/10.1002/admi.202400003