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Diacetato{4′-[4-(benzyloxy)phenyl]-2,2′:6′,2′′-terpyridine}zinc(II)
- Source :
- Acta Crystallographica Section E, Vol 65, Iss 12, Pp m1672-m1672 (2009)
- Publication Year :
- 2009
- Publisher :
- International Union of Crystallography, 2009.
-
Abstract
- In the title compound, [Zn(CH3COO)2(C28H21N3O)], the ZnII ion is in a trigonal–bipyramidal ZnN3O2 coordination with a tridentate N-chelating 4′-[4-(benzyloxy)phenyl)-2,2′:6′,2′′-terpyridine ligand in the equatorial position and two acetate anions in the axial positions. The three pyridine rings are approximately coplanar, with a maximum deviation of 0.03 Å from the mean plane. The phenoxy substituent makes a dihedral angle of 18.1 (2)° with the central pyridine ring. The benzyl group has a C—O—C—C torsion angle of 77.62 (8)° relative to the phenoxy ring. In the crystal, molecules are linked via C—H...O hydrogen bonds.
- Subjects :
- Crystallography
QD901-999
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 65
- Issue :
- 12
- Database :
- Directory of Open Access Journals
- Journal :
- Acta Crystallographica Section E
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.2c5fc998a4cc49f1ba21d4aa4ecf8ccb
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S1600536809049502