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Diacetato{4′-[4-(benzyloxy)phenyl]-2,2′:6′,2′′-terpyridine}zinc(II)

Authors :
Zhan Guo Lu
Wei Li
Source :
Acta Crystallographica Section E, Vol 65, Iss 12, Pp m1672-m1672 (2009)
Publication Year :
2009
Publisher :
International Union of Crystallography, 2009.

Abstract

In the title compound, [Zn(CH3COO)2(C28H21N3O)], the ZnII ion is in a trigonal–bipyramidal ZnN3O2 coordination with a tridentate N-chelating 4′-[4-(benzyloxy)phenyl)-2,2′:6′,2′′-terpyridine ligand in the equatorial position and two acetate anions in the axial positions. The three pyridine rings are approximately coplanar, with a maximum deviation of 0.03 Å from the mean plane. The phenoxy substituent makes a dihedral angle of 18.1 (2)° with the central pyridine ring. The benzyl group has a C—O—C—C torsion angle of 77.62 (8)° relative to the phenoxy ring. In the crystal, molecules are linked via C—H...O hydrogen bonds.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
65
Issue :
12
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.2c5fc998a4cc49f1ba21d4aa4ecf8ccb
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536809049502