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Evidence for single metal two electron oxidative addition and reductive elimination at uranium

Authors :
Benedict M. Gardner
Christos E. Kefalidis
Erli Lu
Dipti Patel
Eric J. L. McInnes
Floriana Tuna
Ashley J. Wooles
Laurent Maron
Stephen T. Liddle
Source :
Nature Communications, Vol 8, Iss 1, Pp 1-10 (2017)
Publication Year :
2017
Publisher :
Nature Portfolio, 2017.

Abstract

The reactivity of f-block complexes is primarily defined by single-electron oxidations and σ-bond metathesis. Here, Liddle and co-workers provide evidence that a uranium complex can undergo reversible oxidative addition and reductive elimination, demonstrating transition metal-like reactivity within f-block chemistry.

Subjects

Subjects :
Science

Details

Language :
English
ISSN :
20411723
Volume :
8
Issue :
1
Database :
Directory of Open Access Journals
Journal :
Nature Communications
Publication Type :
Academic Journal
Accession number :
edsdoj.2523f3b2e85c4ba3aef12ee29f04b159
Document Type :
article
Full Text :
https://doi.org/10.1038/s41467-017-01363-0