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Crystal structure of (±)-(5SR,6SR)-6-ethenyl-1-[(RS)-1-phenylethoxy]-1-azaspiro[4.5]decan-2-one

Authors :
Takeshi Oishi
Shio Yamamoto
Takashi Yokoyama
Akihiro Kobayashi
Takaaki Sato
Noritaka Chida
Source :
Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 12, Pp 1528-1530 (2015)
Publication Year :
2015
Publisher :
International Union of Crystallography, 2015.

Abstract

In the title compound, C19H25NO2, the pyrrolidine ring adopts an envelope form, with the spiro C atom as the flap, while the cyclohexane ring shows a chair form. A weak intramolecular C—H...O interaction supports the molecular conformation, generating an S(6) ring motif. In the crystal, pairs of C—H...O interactions connect the molecules into inversion dimers with an R22(16) ring motif. The dimers are linked by a second pair of C—H...O interactions, enclosing an R42(12) ring motif, into a tape structure along the b axis.

Details

Language :
English
ISSN :
20569890
Volume :
71
Issue :
12
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E: Crystallographic Communications
Publication Type :
Academic Journal
Accession number :
edsdoj.2386bd12a44bff81c81474000e8815
Document Type :
article
Full Text :
https://doi.org/10.1107/S2056989015021209