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USO DA RMN DE BAIXA RESOLUÇÃO NA AVALIAÇÃO DA DINÂMICA MOLECULAR DO Origanum vulgare

Authors :
Vanessa Cristina dos Santos Peixoto de Oliveira
Maria Inês Bruno Tavares
Eduardo Miguez Bastos da Silva
Bianca Natividade Barreto de Lima
Roberto Pinto Cucinelli Neto
Source :
Química Nova, Vol 38, Iss 3, Pp 351-355 (2015)
Publication Year :
2015
Publisher :
Sociedade Brasileira de Química, 2015.

Abstract

In this work, proton NMR relaxometry was used to measure the behavior of spin-lattice relaxation time with T1H as the time constant, and also of spin-spin relaxation time with the time constant T2H. These relaxometry parameters were determined to better understand the changes in the main structures present in commercial and in nature forms of origanum. The T1H relaxation data showed that the structures which had higher molecular mass were more sensitive to degradation with increased temperature treatment. According to the values of the T2H parameter, up to 150 degrees no significant change in the mobility and organization of water was observed. These data infer that the ideal cooking temperature and tea preparation mode for this herb should be around 100 degrees for the sample not to lose its characteristics. Also, it is not advisable to cook this herb at higher than 150 degrees but better to consume it at room temperature, especially give commercial herb has already been dehydrated.

Details

Language :
English, Spanish; Castilian, Portuguese
ISSN :
16787064 and 01004042
Volume :
38
Issue :
3
Database :
Directory of Open Access Journals
Journal :
Química Nova
Publication Type :
Academic Journal
Accession number :
edsdoj.1f8b58e9ed0047719ac50380d8b3ed0c
Document Type :
article
Full Text :
https://doi.org/10.5935/0100-4042.20150017