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Poly[4,4′-iminodipyridinium [tetra-μ3-oxido-tetraoxido-di-μ4-phosphato-κ4O:O′:O′′:O′′′-tetravanadium(V)]]

Authors :
Robert L. LaDuca
Gregory A. Farnum
Source :
Acta Crystallographica Section E, Vol 64, Iss 12, Pp m1602-m1602 (2008)
Publication Year :
2008
Publisher :
International Union of Crystallography, 2008.

Abstract

In the title salt, {(C10H11N3)[V4O8(PO4)2]}n, cubane-like [V4O8]4+ clusters are connected by phosphate anions into anionic [V4P2O16]n2n− layers. These aggregate into the three-dimensional structure via N—H...O hydrogen-bonding mechanisms imparted by 4,4′-iminodipyridinium dications situated between the layers.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
64
Issue :
12
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.1b7091a915e34c01a5e83e55a4b049c1
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536808038348