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(E,Z)-1-(4-Chlorophenyl)-5-phenyl-5-(phenylsulfanyl)penta-2,4-dien-1-one

Authors :
Anna V. Vologzhanina
Dmitry M. Gusev
Alexander A. Golovanov
Valentina S. Pisareva
Source :
Acta Crystallographica Section E, Vol 69, Iss 9, Pp o1479-o1479 (2013)
Publication Year :
2013
Publisher :
International Union of Crystallography, 2013.

Abstract

The penta-2,4-dien-1-one fragment of the title compound, C23H17ClOS, is twisted by 20.0 (3)°, as measured by the dihedral angle between the planes of the carbonyl group and its attached C atom and the distant C=C double bond and its attached C atom. The 4-chlorophenyl group forms a dihedral angle of 4.0 (3)° with the adjacent carbonyl group. Conjugation between the phenyl ring and the C=C double bond is absent; the dihedral angle between the phenyl ring and the C—C=C fragment is 34.3 (2)°. In the crystal, molecules are linked via C—H...O hydrogen bonds, forming chains parallel to the b-axis direction.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
69
Issue :
9
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.1686bff4f7324d59a55c0d4d0a1245e3
Document Type :
article
Full Text :
https://doi.org/10.1107/S160053681302312X