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Crystal structure of (4Z)-4-[(2E)-3-(2-chlorophenyl)-1-hydroxyprop-2-en-1-ylidene]-3-methyl-1-phenyl-1H-pyrazol-5(4H)-one

Authors :
Muhammad Shahid
Munawar Ali Munawar
Muhammad Nawaz Tahir
Muhammad Salim
Khizar Iqbal Malik
Source :
Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 6, Pp o407-o408 (2015)
Publication Year :
2015
Publisher :
International Union of Crystallography, 2015.

Abstract

In the title compound, C19H15ClN2O2, the pyrazole ring is almost planar (r.m.s. deviation = 0.002 Å) and subtends dihedral angles of 5.31 (16) and 1.86 (16)° with the phenyl and chlorobenzene rings, respectively. An intramolecular O—H...O hydrogen bond closes an S(6) ring and a short C—H...O contact is also observed. In the crystal, molecules are linked by weak C—H...O interactions to generate (001) sheets. Weak aromatic π–π interactions between the chlorobenzene and pyrazole rings, with a centroid–centroid distance of 3.7956 (17) Å are also observed.

Details

Language :
English
ISSN :
20569890
Volume :
71
Issue :
6
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E: Crystallographic Communications
Publication Type :
Academic Journal
Accession number :
edsdoj.133226dc4355481daf6dc1d831417e49
Document Type :
article
Full Text :
https://doi.org/10.1107/S2056989015009020